WordReference Random House Unabridged Dictionary of American English © 2019
Lju•blja•na  (lo̅o̅′blē änə; Slovene. lyo̅o̅blyä nä),USA pronunciation n. 
  1. Place Namesa city in and the capital of Slovenia, in the central part. 305,211. German,  Laibach. 

Collins Concise English Dictionary © HarperCollins Publishers::

Ljubljana /luːˈbljɑːnə/ n
  1. the capital of Slovenia: capital of Illyria (1816–49); part of Yugoslavia (1918–91); university (1595). Pop: 265 881 (2002)
    German name: Laibach

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