Ordovician
Concise Oxford English Dictionary © 2008 Oxford University Press:
Ordovician /ˌɔːdəˈvɪʃɪən/
▶adjective Geology relating to or denoting the second period of the Palaeozoic era (between the Cambrian and Silurian periods, about 510 to 439 million years ago), a time when the first vertebrates appeared.
'Ordovician' also found in these Oxford entries:

